catena-Poly[[trimethyltin(IV)]-μ-cyclohex-3-ene-1-carboxylato]
نویسندگان
چکیده
منابع مشابه
catena-Poly[[trimethyltin(IV)]-μ-cyclohex-3-ene-1-carboxylato]
The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H⋯O...
متن کاملcatena-Poly[sodium [[tris(3-methylpyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordin-ated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxyl-ate-O atoms and four pyridine-N atoms. One of the carboxyl-ate ligands bridges the Eu cations, forming a one-dimensional coordination polymer along the b axis. The Eu-O bond distances lie withi...
متن کاملcatena-Poly[[(aqualithium)-μ-3-carboxypyrazine-2-carboxylato-κ4 O 2,N 1:O 3,N 4] monohydrate]
The polymeric structure of the title compound {[Li(C(6)H(3)N(2)O(4))(H(2)O)]·H(2)O}(n), contains two symmetry-independent Li(I) complex units, both having distorted trigonal-bipyramidal coordination environments. The Li(I) ions are bridged by both the N and O atoms of the ligands, generating two symmetry-independent polymeric chains propagating along the b-axis direction. In both ligands, the s...
متن کاملcatena-Poly[[bis(1-methylimidazole-κN 3)zinc(II)]-μ-isophthalato-κ2 O 1:O 3]
In the solid state, the title compound, [Zn(C(8)H(4)O(4))(C(4)H(6)N(2))(2)](n), exhibits the existence of polymeric zigzag chains extending along the a axis. Each Zn(II) ion is coordinated by two N atoms [Zn-N = 1.996 (6) and 2.032 (5) Å] and two O atoms [Zn-O = 1.930 (4) and 1.976 (4) Å] in a distorted tetra-hedral geometry. Weak C-H⋯O inter-actions contribute to the crystal packing stability.
متن کاملcatena-Poly[[diaquacobalt(II)]-bis(μ-3-carboxyadamantane-1-carboxylato-κ2 O 1:O 3)]
In the title compound, [Co(C(12)H(15)O(4))(2)(H(2)O)(2)](n), adjacent Co(II) atoms ( symmetry) are bridged by 3-carboxy-adamantane-1-carboxyl-ate anions, forming a chain running along [001]. Inter-chain O-H⋯O hydrogen bonds link the chains into layers parallel to (100); the layers are further connected via inter-layer hydrogen bonds inter-actions, forming a three-dimensional framework.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809054403